By William M. Ayers
content material: resources and economics of carbon dioxide / Sol J. Barer and Kenneth M. Stern --
Carbon dioxide equilibria / James N. Butler --
Coordination of carbon dioxide to nickel : another theoretical version / R.P. Messmer and H.-J. Freund --
Metal-induced modifications of carbon dioxide / Donald J. Darensbourg, Christopher G. Bauch, and Cesar Ovalles --
Use of stoichiometric reactions within the layout of redox catalyst for carbon dioxide relief / Daniel L. DuBois and Alex Miedaner --
Electrocatalytic carbon dioxide aid / B. Patrick Sullivan, Mitchell R.M. Bruce, Terrence R. O'Toole, C. Mark Bolinger, Elise Megehee, Holden Thorp, and Thomas J. Meyer --
Enzymatic activation of carbon dioxide / Leland C. Allen --
Adsorptive and catalytic homes of carbon monoxide and carbon dioxide over supported steel oxides / D.G. Rethwisch and J.A. Dumesic --
Adsorption and response of carbon dioxide on zirconium dioxide / Ronald G. Silver, Nancy B. Jackson, and John G. Ekerdt --
impression of potassium at the hydrogenation of carbon monoxide and carbon dioxide over supported Rh catalysts / S.D. Worley and C.H. Dai --
Carbon dioxide aid with an electrical box assisted hydrogen insertion response / W.M. Ayers and M. Farley --
Electrochemical relief of aqueous carbon dioxide at electroplated Ru electrodes : investigations towards the mechanism of methane formation / Karl W. Frese, Jr. and David P. Summers --
Electrochemical experiences of carbon dioxide and sodium formate in aqueous ideas / M.H. Miles and A.N. Fletcher --
Electrochemical activation of carbon dioxide / okay. Chandrasekaran and J. O'M. Bockris.
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Extra resources for Catalytic Activation of Carbon Dioxide
11. ; Yamamoto, A. : Toyko, Japan, 1982, p 79. 12. Darensbourg, D. J . ; Ovalles, C. Chem. Tech. 1985, 15, 636. 13. Chem. Eng. News, 1985, 63, 10. 14. Czoukowski, M. ; Bayne, A. R. Hydrocarbon Process. 1980, 59, 103. 15. Leonard, J. D. S. Patent 4 299 981 (1981). 16. Ikaraski, T. Chem. Economy & Eng. Rev. 1980, 12, 31 17. Darensbourg, D. ; Rokicki, A. Organometallics 1982, 1, 1685. 18. Slater, S. ; Schumann, B. ; Darensbourg, M. Organometallics 1982, 1, 1662. 19. Darensbourg, D. J . ; Darensbourg, M.
Nobile, C. F. J. Chem. Soc. Dalton Trans. 1977, 708. ; Steinmann, M. Angew. Chem. 1982, 94, 526. Jordan, K. D. J. Phys. Chem. 1984, 88, 2459. Kafafi, Z. ; Hange, R. ; Billups, W. ; Margrave, J. L. J. Am. Chem. Soc. 1983, 105, 3886. ch004 Donald J. Darensbourg, Christopher G. Bauch, and Cesar Ovalles Department of Chemistry, Texas A&M University, College Station, TX 77843 The activation of carbon dioxide by homogeneous and heterogeneous metal catalysts, as well as the nature of the stoichiometric insertion processes of these cata lysts, are examined.
5 4. DARENSBOURG ET AL. Metal-Induced 33 Transformations undergone s i g n i f i c a n t advancement, analogous p r o c e s s e s i n v o l v i n g m e t a l - a l k o x i d e s have been l e s s w e l l - i n t e r p r e t e d (32-34). We have r e c e n t l y s y n t h e s i z e d W(C0) 0R~ (R = Ph, C h\CH -m) d e r i v a t i v e s from W(C0) THF and [Et„N][OR] s a l t s (Darensbourg, D. J . ; Sanchez, Κ. ; R h e i n g o l d , A. L. J . Am. Chem. S o c , i n p r e s s ) . I n s o l u t i o n t h e s e s p e c i e s a r e e x t r e m e l y CO l a b i l e , decomposing r e a d i l y t o W„(CO) ( y - 0 R ) ~ i n t h e absence o f a CO atmosphere ( 3 5 ) .