A New Sight towards Dye-sensitized Solar Cells: Material and by Hong Lin

By Hong Lin

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The dual electron transfer pathways given by the sulfur atom residing in the bridge as well as by the carboxylic acid for Zn5S-sensitized TiO2 cell against single pathway for Zn5O-sensitized cell, may accelerate the electron injection from the Zn5S excited singlet state to the CB of the TiO2 electrode, leading to the large IPCE value. The results obtained from optical spectroscopy, DFT calculations, dye coverage, ATR-FTIR spectroscopy, and XPS measurements are in good agreement with the additional electron injection pathway through the interaction between the sulfur atom of the spacer and the TiO2 surface.

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